1500 |
n-C15 |
212 |
- |
- |
1.04 ± 0.05 |
- |
- |
- |
- |
1700 |
n-C17 |
240 |
- |
- |
0.06 ± 0.03 |
- |
0.01 ± 0 |
- |
- |
1738 |
3-MeC17 |
239; 56; 224 |
- |
- |
0.14 ± 0.07 |
- |
- |
- |
- |
2107 |
n-C21 |
296 |
- |
- |
2.33 ± 0.26 |
0.09 ± 0.04 |
0.1 ± 0.03 |
- |
- |
2207 |
n-C22 |
310 |
- |
- |
2.49 ± 0.14 |
- |
0.82 ± 0.24 |
- |
0.06 ±
0.03 |
2270 |
4-MeC22 |
309; 70; 280 |
- |
- |
1.03 ± 0.15 |
- |
- |
- |
- |
2280 |
C23-ene1 |
322 |
- |
- |
- |
- |
0.21 ± 0.06 |
- |
1.13 ±
0.46 |
2287 |
C23-ene2 |
322 |
- |
- |
- |
- |
0.06 ± 0.02 |
- |
0.07 ±
0.04 |
2310 |
n-C23 |
324 |
0.07 ± 0.07 |
- |
13.48 ± 1.12 |
0.07 ± 0.02 |
7.57
± 0.71 |
- |
7.97 ± 1.38 |
2343 |
9-; 11-;13-MeC23 |
323; 140; 224; 168; 196; |
0.01 ± 0.02 |
- |
0.83 ± 0.22 |
0.01 ± 0.01 |
0.56 ± 0.18 |
- |
0.39 ± 0.18 |
2349 |
7-MeC23 |
323; 112; 252 |
- |
- |
- |
- |
0.09 ± 0.03 |
- |
- |
2371 |
4-MeC23 |
323; 70; 294 |
- |
- |
3.45 ± 0.2 |
- |
0.89 ± 0.26 |
- |
1.46 ± 0.56 |
2379 |
7,11-;7,13-DiMeC23 |
309; 112; 266; 182; 196; 210; 168 |
- |
- |
- |
- |
0.08 ± 0.02 |
- |
- |
2380 |
3-MeC23 |
323; 56; 308 |
0.02 ± 0.03 |
- |
3.24 ± 0.19 |
0.04 ±
0.02 |
0.55 ± 0.13 |
- |
- |
2380 |
C24-ene1 |
336 |
- |
- |
- |
- |
- |
- |
0.59 ±
0.25 |
2386 |
C24-ene2 |
336 |
- |
- |
- |
- |
0.09 ± 0.03 |
- |
- |
2394 |
C24-ene3 |
336 |
- |
- |
- |
- |
0.12 ± 0.04 |
- |
- |
2409 |
n-C24 |
338 |
- |
- |
4.79 ± 0.44 |
1.88 ± 0.39 |
3.33 ± 0.49 |
0.03 ± 0.03 |
5.92 ± 1.62 |
2442 |
10-;12-;14-MeC24 |
337; 154; 224; 182; 196; 210; 168 |
- |
- |
0.11 ± 0.04 |
0.15 ± 0.11 |
0.66 ± 0.16 |
0.1 ± 0.09 |
1.01 ±
0.37 |
2463 |
C25-ene1 |
350 |
- |
- |
- |
- |
- |
- |
0.22 ±
0.1 |
2473 |
4-MeC24 |
337; 70; 308 |
- |
- |
4.24 ± 1.16 |
4.11 ± 0.16 |
2.63
± 0.36 |
0.22 ± 0.2 |
11.79 ± 2.02 |
2483 |
C25-ene2 |
350 |
- |
- |
3.41 ± 0.62 |
- |
- |
- |
7.84 ±
0.82 |
2483 |
C25-diene1 |
348 |
- |
- |
- |
- |
3.93 ± 0.99 |
- |
7.43 ±
1.05 |
2480 |
3-MeC24 |
337; 56; 322 |
- |
- |
- |
0.31 ± 0.02 |
- |
- |
- |
2484 |
C25-ene3 |
350 |
- |
0.01 |
- |
- |
3.84 ± 0.85 |
- |
- |
2492 |
C25-ene4 |
350 |
- |
- |
- |
- |
1.77 ± 0.36 |
- |
- |
2509 |
n-C25 |
352 |
0.32 ± 0.17 |
1.15 ± 0.96 |
11.1 ± 0.87 |
10.67 ±
0.4 |
9.49 ± 0.56 |
5.89 ± 5.17 |
12.91 ± 3.24 |
2540 |
C25-diene2 |
348 |
- |
- |
- |
- |
2.22 ± 0.21 |
- |
- |
2542 |
9-;11-;13-;15-MeC25 (+ unsaturated non-CHC compound) |
351; 140;
252; 168; 224; 196; 224, 168 |
0.12 ± 0.1 |
0.13 ± 0.11 |
3.04 ± 0.89 |
6.51 ± 2.83 |
5.26 ± 0.41 |
11.19 ± 10.08 |
11.86 ± 1.83 |
2551 |
7-MeC25 |
351; 112; 280 |
0.03 ± 0.1 |
- |
- |
3.18 ± 0.24 |
1.42
± 0.46 |
- |
2.39 ± 3.95 |
2555 |
C25diene3 |
348 |
- |
- |
6.18 ± 0.93 |
- |
- |
- |
4.41 ±
1.35 |
2562 |
C25diene4 |
348 |
- |
- |
2.48 ± 0.33 |
- |
- |
- |
- |
2557 |
5-MeC25 |
351; 84; 308 |
0.32 ± 0.25 |
1.12 ± 0.76 |
- |
- |
0.39
± 0.07 |
- |
1.29 ± 0.67 |
2577 |
4-MeC25 |
351; 70; 322 |
0.21 ± 0.11 |
6.4 ± 1.81 |
- |
5.69 ±
0.4 |
2.84 ± 0.93 |
12.13 ± 1.52 |
4.29 ± 1.46 |
2575 |
C25diene5 |
348 |
- |
- |
4.31 ± 0.22 |
- |
- |
- |
3.3 ±
1.99 |
2581 |
3-MeC25 |
351; 56; 336 |
0.19 ± 0.11 |
6.28 ± 1.96 |
4.11 ± 0.57 |
5.81 ± 0.58 |
3.94 ± 0.64 |
3.48 ± 2.87 |
6.44 ± 0.62 |
2586 |
5,13-DiMeC25 |
337; 84; 322; 210; 196 |
0.11 ± 0.06 |
- |
- |
- |
- |
- |
- |
2593 |
C26-ene1 |
364 |
- |
- |
- |
- |
2.23 ± 0.57 |
- |
- |
2600 |
C26-ene2 |
364 |
- |
- |
- |
- |
2.52 ± 0.23 |
- |
- |
2608 |
n-C26 |
366 |
0.23 ± 0.13 |
0.82 ± 0.47 |
- |
5.97 ± 0.27 |
4.51
± 0.23 |
2.48 ± 1.75 |
- |
2613 |
3,7-; 3,9-DiMeC25 |
337; 56; 350; 126; 280; 154; 252 |
0.15 ±
0.21 |
0.33 ± 0.36 |
- |
- |
- |
- |
- |
2641 |
12-; 14; 16-MeC26 |
365; 182; 224; 210; 196; 238; 168 |
0.16 ±
0.09 |
3.21 ± 1.15 |
- |
8.66 ± 0.76 |
1.89 ± 1.06 |
2.94 ± 2.17 |
0.36
± 0.14 |
2640 |
C26diene |
362 |
- |
- |
- |
- |
0.53 ± 0.29 |
- |
- |
2645 |
9-MeC26 |
365; 140; 266 |
- |
- |
- |
3.03 ± 0.67 |
- |
- |
- |
2651 |
7-MeC26 |
365; 112; 294 |
- |
- |
- |
0.67 ± 0.1 |
- |
- |
- |
2651 |
6-MeC26 |
365; 98; 308 |
0.02 ± 0.01 |
- |
- |
- |
- |
- |
- |
2656 |
5-MeC26 |
365; 84; 322 |
0.05 ± 0.03 |
0.06 ± 0.03 |
- |
- |
- |
- |
- |
2669 |
4-MeC26 (+ unsaturated non-CHC compound) |
365; 70; 336 |
0.05 ±
0.03 |
0.58 ± 0.24 |
- |
5.21 ± 0.16 |
- |
5.08 ± 0.98 |
0.7 ±
0.29 |
2681 |
3-MeC26 |
365; 56; 350 |
0.07 ± 0.03 |
0.3 ± 0.12 |
- |
0.15 ±
0.06 |
- |
0.15 ± 0.04 |
0.11 ± 0.04 |
2680 |
C27-ene1 |
378 |
- |
- |
2.05 ± 0.61 |
- |
- |
- |
- |
2684 |
C27-ene2 |
378 |
- |
- |
0.6 ± 0.25 |
- |
- |
- |
- |
2689 |
C27diene1 |
376 |
- |
- |
- |
- |
1.48 ± 0.36 |
- |
- |
2694 |
C27diene2 |
376 |
- |
- |
- |
- |
1.95 ± 0.34 |
- |
- |
2699 |
C27-ene3 |
378 |
- |
- |
- |
0.11 ± 0.22 |
2.07 ± 0.36 |
- |
- |
2703 |
C27-ene4 |
378 |
- |
- |
- |
0.11 ± 0.22 |
2.09 ± 1.21 |
- |
- |
2711 |
n-C27 |
380 |
3.92 ± 0.41 |
11.36 ± 3.14 |
5.13 ± 0.25 |
8.01 ±
0.45 |
4.36 ± 0.48 |
8.05 ± 0.98 |
0.15 ± 0.05 |
2744 |
9-; 11-; 13-; 15-MeC27 |
379; 140; 280; 168; 252; 196; 224 |
5.04
± 0.75 |
26.96 ± 19.32 |
- |
13.39 ± 0.75 |
1.01 ± 0.26 |
20.47 ± 3.31 |
0.05 ± 0.03 |
2742 |
C27diene3 |
376 |
- |
- |
- |
- |
5.48 ± 0.28 |
- |
- |
2752 |
C28diene1 |
390 |
- |
- |
0.61 ± 0.14 |
- |
- |
- |
- |
2756 |
C27diene4 |
376 |
- |
- |
0.69 ± 0.32 |
- |
0.48 ± 0.42 |
- |
0.11 ± 0.11 |
2756 |
7-MeC27 |
379; 112; 308 |
- |
- |
- |
1.26 ± 0.31 |
- |
0.22 ±
0.49 |
- |
2761 |
5-MeC27 |
379; 84; 336 |
3.6 ± 0.47 |
6.37 ± 1.74 |
- |
- |
- |
- |
- |
2760 |
C27diene5 |
376 |
- |
- |
- |
- |
0.97 ± 0.26 |
- |
- |
2770 |
11,13-; 11,15-; 11,17-; 13,15-; 13,17-; 15,17-DiMeC27 |
365; 168;
266; 210; 224; 238; 196 |
1.67 ± 0.54 |
0.91 ± 0.48 |
- |
4.3 ± 0.99 |
- |
- |
- |
2775 |
4-MeC27 |
379; 70; 350 |
- |
- |
- |
- |
1.01 ± 0.29 |
11.18 ±
3.67 |
- |
2775 |
9,15-: 9.17-DiMeC27 |
365; 140; 294; 238; 196; 266; 168 |
- |
- |
- |
5.35 ± 0.77 |
- |
- |
- |
2779 |
C27diene6 |
376 |
- |
- |
- |
- |
2.71 ± 0.15 |
- |
- |
2786 |
3-MeC27 |
379; 56; 364 |
3.24 ± 0.31 |
8.59 ± 1.62 |
- |
0.85 ±
0.49 |
2.28 ± 0.2 |
6.76 ± 2.96 |
- |
2784 |
C28diene2 |
390 |
- |
- |
- |
- |
0.4 ± 0.08 |
- |
- |
2792 |
5,17-DiMeC27 |
365; 84; 350; 266; 168 |
0.58 ± 0.1 |
7.12 ± 1.3 |
- |
- |
- |
- |
- |
2790 |
5,15-DiMeC27 |
365; 84; 350; 238; 196 |
0.12 ± 0.36 |
1.82 ± 1.06 |
- |
- |
0.48 ± 0.37 |
- |
- |
2791 |
5,9-; 5,11-; 5,13-DiMeC27 |
365; 84; 350; 154; 280; 182; 252;
210; 224 |
2.53 ± 0.57 |
- |
- |
- |
- |
- |
- |
2802 |
C28-ene |
392 |
- |
- |
- |
- |
1.01 ± 0.39 |
- |
- |
2813 |
n-C28 |
394 |
2.35 ± 1.3 |
3.3 ± 1.21 |
- |
1.31 ± 0.77 |
0.28 ±
0.08 |
0.57 ± 0.43 |
- |
2814 |
3,9-; 3,11-DiMeC27 |
365; 56; 378; 154, 280; 282; 252 |
2.91 ±
0.61 |
0.06 ± 0.19 |
- |
- |
- |
- |
- |
2816 |
3,7-DiMeC27 |
365; 56; 378; 126; 308 |
1.46 ± 0.58 |
3.8 ± 1.48 |
- |
- |
- |
- |
- |
2841 |
11-; 13-MeC28 |
393; 168; 266; 196; 238 |
- |
- |
- |
- |
- |
1.85 ± 2.3 |
- |
2840 |
12-; 14-MeC28 |
393; 182; 252; 210; 224 |
2.66 ± 0.63 |
1.41 ±
0.58 |
- |
- |
- |
- |
- |
2843 |
3,9,11-; 3,9,13-; 3,9,15-; 3,9,17-TriMeC27 |
393; 56; 392; 154;
294; 196; 252; 224; 280; 168 |
0.88 ± 0.39 |
- |
- |
- |
- |
- |
- |
2853 |
6-MeC28 |
393; 98; 336 |
0.57 ± 0.22 |
0.07 ± 0.04 |
- |
- |
- |
- |
- |
2858 |
5-MeC28 |
393; 84; 350 |
0.68 ± 0.23 |
- |
- |
- |
- |
- |
- |
2864 |
C29diene1 |
404 |
- |
- |
- |
- |
0.16 ± 0.05 |
- |
- |
2868 |
4-MeC28 |
393; 70; 364 |
2.84 ± 0.74 |
0.27 ± 0.12 |
- |
- |
- |
0.49 ± 0.48 |
- |
2874 |
C29-ene1 |
406 |
- |
2.16 ± 1.06 |
- |
- |
- |
- |
- |
2881 |
C29-ene2 |
406 |
1.21 ± 0.79 |
- |
0.84 ± 0.35 |
- |
2.04 ± 2.12 |
0.07 ± 0.09 |
- |
2880 |
C29diene2 |
404 |
- |
0.3 ± 0.14 |
- |
- |
- |
- |
- |
2883 |
C29diene3 |
404 |
- |
- |
- |
- |
4.09 ± 0.28 |
- |
- |
2882 |
3-MeC28 |
393; 56; 378 |
2.27 ± 1.03 |
- |
- |
- |
- |
- |
- |
2887 |
5,9-; 5,11-; 5,13-; 5,15-; 5,17-DiMeC28 |
379; 84; 364; 154; 294;
182; 266; 210; 238 |
0.48 ± 0.21 |
- |
- |
- |
- |
- |
- |
2894 |
C29-ene3 |
406 |
- |
- |
- |
- |
0.12 ± 0.02 |
- |
- |
2897 |
4,10-; 4,12-; 4,14-; 4,16-; 4,18-; 4,20-DiMeC28 |
379; 70; 378;
168; 280; 196; 252; 224; 308; 140 |
0.83 ± 0.61 |
- |
- |
- |
- |
- |
- |
2909 |
n-C29 |
408 |
4.26 ± 0.9 |
0.51 ± 0.24 |
1.64 ± 0.36 |
2.96 ±
1.53 |
0.34 ± 0.11 |
0.23 ± 0.17 |
- |
2920 |
3,7-; 3,9-; 3,11-DiMeC28 |
479; 56; 392; 126; 322; 154; 294; 182;
266 |
1.48 ± 0.54 |
- |
- |
- |
- |
- |
- |
2940 |
11-; 13-; 15-MeC29 |
407; 168; 280; 196; 252; 224 |
7.25 ± 0.51 |
1.87 ± 0.88 |
- |
- |
0.07 ± 0.02 |
5.96 ± 8.04 |
- |
2953 |
7-; 9-MeC29 |
407; 112; 336; 140; 308 |
3.26 ± 1.16 |
0.64 ± 0.3 |
- |
- |
- |
- |
- |
2964 |
5-MeC29 |
407; 84; 364 |
4.4 ± 4.32 |
- |
- |
- |
0.02 ± 0.02 |
- |
- |
2979 |
11,17-; 11,19-; 11,21-; 13,17-; 13,19-DiMeC29 |
393; 168; 294;
266; 196; 322; 140; |
2.14 ± 1.19 |
- |
- |
- |
- |
- |
- |
2983 |
7,11-DiMeC29 |
393; 112; 350; 182; 280 |
1.91 ± 0.85 |
- |
- |
- |
- |
- |
- |
2985 |
7,17-DiMeC29 |
393; 266; 196 |
- |
0.14 ± 0.09 |
- |
- |
- |
- |
- |
2986 |
3-MeC29 |
407; 56; 392 |
4.8 ± 0.67 |
0.08 ± 0.03 |
- |
0.14 ±
0.09 |
- |
0.47 ± 0.47 |
- |
2994 |
5,9-; 5,11-; 5,13-DiMeC29 |
393; 84; 378; 154; 308; 182; 280;
210; 252 |
1.98 ± 0.48 |
0.1 ± 0.06 |
0.02 ± 0.04 |
- |
- |
- |
- |
3013 |
3,7-DiMeC29 |
393; 56; 406; 126; 336 |
- |
0.45 ± 0.23 |
- |
- |
- |
- |
- |
3019 |
3,9-; 3,11-DiMeC29 |
393; 56; 406; 154; 308; 182; 280 |
6.44 ±
0.76 |
- |
0.03 ± 0.07 |
- |
- |
- |
- |
3031 |
3,7-DiMeC29 |
393; 56; 406; 126; 336 |
0.63 ± 0.31 |
- |
- |
- |
- |
- |
- |
3041 |
3,7,11-; 3,7,13-; 3,7,15-; 3,7,17-; 3,9,11-; 3,9,13-; 3,9,15-;
3,9,17-TriMeC29 |
421; 56; 420; 126; 350; 196; 280; 224; 252; 280; 196;
154; 322; |
4.4 ± 0.68 |
- |
- |
- |
- |
- |
- |
3061 |
14,18-; 14-22-DiMeC30 |
407; 210; 266; 280; 196; 336; 140; |
0.86
± 0.43 |
- |
- |
- |
- |
- |
- |
3063 |
4-MeC30 |
421; 70; 392 |
0.34 ± 0.24 |
- |
- |
- |
- |
- |
- |
3075 |
C31ene |
434 |
0.18 ± 0.11 |
0.01 ± 0.02 |
- |
- |
- |
- |
- |
3076 |
C31diene |
432 |
- |
- |
- |
- |
0.25 ± 0.13 |
- |
- |
3080 |
5,9-; 5,11-; 5,13-; 5,15-DiMeC30 |
407; 84; 392; 154; 322; 182;
294; 210; 266; 238 |
0.17 ± 0.09 |
0.03 ± 0.1 |
- |
- |
- |
- |
- |
3088 |
4,8-; 4,10-; 4,12-DiMeC30 |
407; 70; 406; 140; 336; 168; 308;
196; 280 |
2.39 ± 0.86 |
0.01 ± 0.04 |
- |
- |
- |
- |
- |
3102 |
3,9-; 3,11-DiMeC30 |
407; 56; 420; 154; 322; 182; 294 |
0.59 ±
0.41 |
- |
- |
- |
- |
- |
- |
3112 |
4,8,12-; 4,8,14-; 4,8,16-TriMeC30 (+ acetic acid) |
435; 70; 420;
140, 350; 210; 280; 238, 252; 266; 224 |
0.16 ± 0.12 |
- |
- |
- |
- |
- |
- |
3130 |
11-; 13-; 15-MeC31 |
435; 168; 308; 196; 280; 224; 252 |
3.13 ±
0.76 |
- |
- |
- |
- |
- |
- |
3154 |
13,17-; 15,17-DiMeC31 |
421; 196; 294; 266; 224 |
2.16 ± 1 |
0.11
± 0.38 |
- |
- |
- |
- |
- |
3178 |
5,9-;5,11-; 5,13-; 5,15-;5,17-DiMeC31 |
421; 84; 406; 154; 336;
182; 308; 210; 280; 238; 252; 266; 224 |
1.83 ± 0.66 |
- |
- |
- |
- |
- |
- |
3203 |
3,9-; 3,11-; 3,13-; 3,15-DiMeC31 |
421; 56; 434; 154; 336; 182;
308; 210; 280; 238; 252 |
0.52 ± 0.25 |
0.01 ± 0.03 |
0.01 ± 0.03 |
- |
0.02 ± 0.02 |
- |
- |
3477 |
C35-ene |
490 |
- |
- |
- |
- |
0.12 ± 0.04 |
- |
- |
3531 |
11-MeC35 |
491; 168; 364 |
- |
- |
- |
- |
- |
- |
0.55 ±
0.31 |
3629 |
12-MeC36 |
505; 182; 364 |
- |
- |
- |
- |
- |
- |
0.09 ±
0.06 |
3729 |
11-; 13-MeC37 |
519; 168; 392; 196; 364 |
- |
- |
0.05 ± 0.05 |
- |
- |
- |
2.28 ± 1.11 |
3751 |
11,15-DiMeC37 |
505; 168; 406; 238; 336 |
- |
- |
- |
- |
- |
- |
0.45 ± 0.23 |
3774 |
5,15-; 5,17-DiMeC37 |
505; 84; 490; 236; 336; 266; 308 |
- |
- |
- |
- |
- |
- |
0.65 ± 0.33 |
3840 |
C39diene |
544 |
- |
- |
0.28 ± 0.1 |
- |
- |
- |
- |
3876 |
C39-ene |
546 |
- |
- |
2.24 ± 0.18 |
- |
- |
- |
- |
3927 |
11-;13-;15-MeC39 |
547; 168; 420; 168; 392; 224; 364 |
- |
- |
2.74 ± 0.41 |
- |
0.06 ± 0.02 |
- |
0.8 ± 0.37 |
3949 |
11,15-DiMeC39 |
533; 168; 434; 238; 364 |
- |
- |
- |
- |
- |
- |
0.57 ± 0.26 |
3953 |
13,17-DiMeC39 |
533; 196; 406; 266; 336 |
- |
- |
0.24 ± 0.06 |
- |
- |
- |
- |
3973 |
5,15-; 5,17-DiMeC39 |
533; 84, 518; 238; 364; 266; 336 |
- |
- |
- |
- |
- |
- |
0.32 ± 0.16 |
4054 |
C41diene |
572 |
- |
- |
5.32 ± 0.18 |
- |
- |
- |
- |
4074 |
C41-ene |
574 |
- |
- |
1.92 ± 0.5 |
- |
- |
- |
- |
4084 |
C41-ene |
574 |
- |
- |
2.49 ± 0.36 |
- |
- |
- |
- |
4143 |
11-; 13-; 15-; 17-MeC41 |
575; 168; 448; 196; 420; 224, 392; 252;
364 |
1.72 ± 1.2 |
0.52 ± 0.37 |
0.62 ± 0.23 |
- |
0.11 ± 0.03 |
- |
0.02 ± 0.04 |
4173 |
13,15-; 13,17-DiMeC41 |
561; 196; 434; 238; 392; 266; 364 |
0.99
± 1.52 |
0.6 ± 1.98 |
0.58 ± 0.15 |
- |
- |
- |
- |